Except in DOS mode you don't have long file name support, meaning that parts of windows will be broken since many references (e.g. to "program files" won't match up...
Unless you unzip the stuff onto the drive from within another windows installation, but then there's still the matter of making the drive bootable to the OS in the first place.
Unless you unzip the stuff onto the drive from within another windows installation, but then there's still the matter of making the drive bootable to the OS in the first place.