There are loads of stinkers so watch out, but also some total gems that'll keep you going for ages: some that I bought (from memory):
Tomb Raider
Ridge Racer 2
Rage Racer
Pademonium (great platformer)
Crash Bandicoot (cool fun)
Die Hard Trilogy
Tekken 2
Alien Trilogy (looks a bit poor now compared to modern FPS but I liked it at the time)
Final Fantasy VII
Wipeout (and 2097)
I'm sure there were loads more but that's all I can remember now.
Tomb Raider
Ridge Racer 2
Rage Racer
Pademonium (great platformer)
Crash Bandicoot (cool fun)
Die Hard Trilogy
Tekken 2
Alien Trilogy (looks a bit poor now compared to modern FPS but I liked it at the time)
Final Fantasy VII
Wipeout (and 2097)
I'm sure there were loads more but that's all I can remember now.